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Difference between Prevail on someone and Prevail over someone

prevail on someone —(also: prevail with someone) persuade a person (to do smth.):

  • She had turned a deaf ear to the persuasions by which they sought to prevail on her.

prevail over someone —(liter.) gain victory or achieve superiority over a person (also: prevail against someone):

  • The heroes of these films inevitably prevail over their villainous opponents.